The theoretical value of A** can be calculated using A** = 4πm*qk 2/h 3, where h is Planck’s constant. For BAY 11-7082 in vivo n-type GaN, m* = 0.22m o is the effective electron mass for GaN and the value of A** is determined to be 26.4 A/(cm2K2). Zhou et al. [21] also reported
that the value of A** determined by a modified Richardson plot in the GaN material is close to the theoretical value. The values were calculated using both values of σ so obtained GW3965 in vitro for the temperature ranges of 100 to 220 and 220 to 340 K. Thus, in Figure 6, the circles represent the plot calculated with σ so = 90 mV (straight line 1) in the temperature range of 100 to 200 K, and the squares represent the plot calculated with σ so = 176 mV (straight line 2) in the temperature range of 200 to 380 QNZ molecular weight K. The best linear fits to the modified experimental data are depicted by solid lines in Figure 6 which represent the true activation energy plots in respective temperature ranges. The calculations have yielded zero-bias mean SBH ϕ bo of 0.92 eV (in the range of 100 to 220 K) and 1.82 eV (in the range of 220 to 340 K). In Figure 6, the intercepts at the ordinate give the Richardson constant A** as 72.4 A/(cm2K2) (in the range of 100 to 220 K) and 32.2A/(cm2K2) (in the range of 220 to 340 K) without using the temperature coefficient
of the SBHs. This value of the Richardson coefficient at room temperature is close to the theoretical value 26.4A/(cm2K2) [14, 16–20, 23]. It can be pointed out that although a barrier inhomogeneity is visible in Pt/GaN diodes, But highlighting
feature of these diodes, is high Schottky barrier height observed. The quality of the metal–semiconductor interface is affected by the process steps and deposition vacuum since contamination and oxide layer growth at the interface may result in SBH reduction and high leakage current by inducing local nanoscopic patches of low barrier heights. Studies by Iucolano et al. revealed that this kind of inhomogeneous behavior is observed in all semiconductors and results in overall decreased barrier heights [10]. The contamination level and oxide layer can be minimized by following fabrication steps in a clean room and depositing 2-hydroxyphytanoyl-CoA lyase Schottky metals in UHV. By selecting high work function metal Pt, a high gate potential can be achieved. These kinds of high barrier heights are suitable for many high-power and switching applications. The reverse characteristics of these devices are also quite good as compared to those of other Schottky metal combinations. Very low reverse leakage current and high breakdown voltages are good for high-power applications where losses should be low. A high rectifying ratio is desired for switching applications. These diodes are better in terms of observed Schottky barrier height and reverse characteristics. Figure 6 Modified Richardson plot, [ln( I 0 / T 2 ) - q 2 σ so 2 /2 k 2 T 2 ] versus 1/ T , for the Pt/n-GaN Schottky diode.